基于氧气回收的超临界水氧化工艺优化
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国家自然科学基金项目(51706049);中国科学院青年创新促进会会员(2017412);广东省自然科学基金项目(2014A030310203);南 沙区技术开发项目(2015KF013);广州市科学研究专项(201707010407)

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Optimization of a Supercritical Water Oxidation Process with Oxygen Recovery
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    摘要:

    针对超临界水氧化系统中氧气过量造成的运行费用过高问题,该文研究了一种基于高压水吸收原理的氧气回收方法。基于 PSRK 模型,通过 Aspen Plus 方法建立了基于氧气回收的超临界水氧化系统模拟流程,分析了超临界水氧化系统中高压气液分离器内压力和温度等参数对 O2 和 CO2 分离效 果的影响。结果显示,随着高压气液分离器内压力的升高,气相中 O2 的纯度增加,但 O2 进入气相的比例下降。当温度升高时,O2 进入气相的比例缓慢上升,但气相中 O2 的纯度下降。当高压气液分离器内压力为 8 MPa、温度为 27℃ 时,O2 进入气相的比例为 89.29%,气相中 O2 的纯度可达 83.33%。对系统的物料能耗成本分析结果显示,当过氧量系数为 2 时,基于氧气回收的超临界水氧化系统物料 能耗成本为 2.811 元/kgCOD(化学需氧量),同比下降21.01%,且随着过氧量系数的增加,系统的物料能耗成本同比下降趋势变大。

    Abstract:

    Excess oxygen in the supercritical water oxidation systems usually causes the problem of system operation cost improvement. To solve this problem, a high pressure water absorption principle based method was investigated for the O2 recycle. The Aspen Plus process of supercritical water oxidation system with oxygen recovery and the PSRK model was applied to study the influence of system parameters like pressure and temperature. The analyzing results showed that, with increasing pressure the purity of O2 can be increased but the O2 yield was decreased in the gas phase. With the increasing temperature, the ratio of O2 in gas phase can be increased but the purity of O2 was decreased. When the separator pressure and temperature were set to 8 MPa and 27℃, the ratio and purity of O2 was 89.29% and 83.33% respectively. The material and energy consumption cost of the system was calculated, and the results showed that the material and energy consumption cost was 2.811 ¥/kg chemical oxygen demand (COD). The cost can be reduced 21.01% in comparison with existing supercritical water oxidation system with oxygen recovery. Moreover, the reduction rate of the material and energy consumption cost increases gradually with the increasing of excess oxygen coefficient.

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引文格式
陈久林,张凤鸣,苏闯建,等.基于氧气回收的超临界水氧化工艺优化 [J].集成技术,2018,7(3):62-71

Citing format
CHEN Jiulin, ZHANG Fengming, SU Chuangjian, et al. Optimization of a Supercritical Water Oxidation Process with Oxygen Recovery[J]. Journal of Integration Technology,2018,7(3):62-71

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  • 在线发布日期: 2018-05-18
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