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分子聚集发光——过去、现在、未来

Molecule Aggregate Luminescence: Past, Present, and Future

  • 摘要: 在光物理学与材料科学交融的历史脉络中,分子聚集发光现象的发现与研究,标志着对物质发光行为认知的一次深刻范式转移,也是多学科交叉推动集成技术创新的一个典范。本文系统回顾了聚集诱导发光、簇发光及余辉发光等核心机制的揭示与完善过程,聚焦于其在环境检测、食品安全与生命健康等传统优势领域的进展,重点剖析分子聚集发光在“信息处理与储存、先进探测与指示、能源利用与转化”这三个集成技术创新方向的前瞻性应用。在信息领域,其多刺激响应特性正推动防伪加密从静态图案走向动态、高维的智能安全系统,展现了材料与信息技术集成的巨大潜力;在探测领域,其高灵敏度与可视化优势,与传感、成像技术深度融合,催生了从痕量爆炸物、毒品到潜指纹的现场快检新技术;在能源领域,其高效的光热转换与光谱调控能力,为太阳能海水淡化及光合生物固碳增效提供了新途径,体现了光-热-化能量转换的系统集成。展望未来十年,分子聚集发光领域将超越单一功能材料的开发,迈向诊疗一体化的动态精准医疗、四维动态信息加密、人工智能赋能的阵列传感,以及光-生物耦合的合成细胞工厂等跨学科融合新纪元。

     

    Abstract: Within the historical interplay of photophysics and materials science, the discovery and study of molecular aggregation-induced luminescence mark a profound paradigm shift in understanding the luminescent behavior of matter, and exemplify how interdisciplinary convergence drives innovation in integrated technologies. This review systematically outlines the emergence and development of core mechanisms—including aggregation-induced emission (AIE), clusteroluminescence, and room-temperature phosphorescence (RTP)—and surveys their progress in established applications such as environmental monitoring, food safety, and biomedical science. Emphasis is placed on the forward-looking role of molecular aggregation luminescence in three integrated technological domains: information processing and storage, advanced detection and signaling, and energy utilization and conversion.
    In information technology, the multi-stimuli-responsive properties of these materials are enabling a transition from static patterns to dynamic, high-dimensional intelligent security systems for anti-counterfeiting and encryption, demonstrating strong potential in material-information integration. In detection, their high sensitivity and visualizability, coupled with sensing and imaging techniques, have led to novel on-site assays for trace explosives, drugs, and latent fingerprints. In energy, efficient photothermal conversion and spectral modulation capabilities offer new pathways toward solar desalination and enhanced photosynthetic carbon fixation, highlighting the systemic integration of light–thermal–chemical energy conversion.
    Looking forward, the field is poised to advance beyond single-function materials toward an era of cross-disciplinary integration—encompassing dynamic precision theranostics, four-dimensional dynamic information encryption, artificial-intelligence-augmented sensor arrays, and photo-bio-integrated synthetic cellular factories.

     

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