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基于聚吡咯修饰的碳泡沫可压缩电极材料

Compressible Electrode Material Based on Polypyrrole Decorated Carbonized Melamine Foam

  • 摘要: 在该研究中, 通过高温碳化和原位聚合法制备了基于市售三聚氰胺泡沫和吡咯单体的聚吡咯/碳化三聚氰胺泡沫(Polypyrrole/Carbonized Melamine Foam, PPy/CMF)的可压缩超级电容器电极材料。通过三电极体系在 1 mol/L 高氯酸钠电解液中研究了可压缩 PPy/CMF 电极材料的电化学性质。结果显示, 可压缩电极材料的体积电容在 2 mA/cm3 时可达到 3 168 mF/cm3, 1 000 次充放电循环后可保持原始电容的 86.88%。此外, 该材料的循环伏安曲线和恒流充放电曲线在不同压缩下无显著变化, 表明PPy/CMF 是具有高压缩稳定性的可压缩电极, 适合于超级电容器。以上结果表明, PPy/CMF 可作为可压缩超级电容器的潜在电极材料。

     

    Abstract: In this research, a compressible electrode of polypyrrole/carbonized melamine foam (PPy/CMF) based on commercial melamine foam and pyrrole monomer was fabricated by high temperature carbonization and in-situ polymerization. The electrochemical property of compressible PPy/CMF electrode material was investigated by three-electrode system in 1 mol/L sodium perchlorate electrolyte. The volumetric capacitance MFof compressible electrode material can achieve 3 168 mF/cm3 at 2 mA/cm3 and preserve 86.88% of initial capacitance after 1 000 charge and discharge cycles. Furthermore, cyclic voltammetry and galvanostatic charge-discharge curves of compressible electrode material did not change significantly under different compressions, indicating that PPy/CMF is an appropriate compressible electrode with high compressive stability for supercapacitor. These results demonstrate that PPy/CMF is an excellent candidate for compressible supercapacitor.

     

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